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EN ISO 6145-11:2008

Current

Current

The latest, up-to-date edition.

Gas analysis - Preparation of calibration gas mixtures using dynamic volumetric methods - Part 11: Electrochemical generation (ISO 6145-11:2005)

Published date

20-08-2008

Foreword
Introduction
1 Scope
2 Normative references
3 Procedure
  3.1 Principle
  3.2 Complementary gas
  3.3 Electrolytic systems for gas generation
  3.4 Apparatus
      3.4.1 Cell construction
      3.4.2 Current supply and gas flow control
  3.5 Gas mixture preparation
      3.5.1 Complementary gas
      3.5.2 Voltage supply
      3.5.3 Calculation of gas mixture content
4 Uncertainty evaluation
  4.1 Introduction
  4.2 Sources of uncertainty
      4.2.1 Complementary gas flow
      4.2.2 Gas generation
      4.2.3 Absorption of generated gas in the cell
            electrolyte
      4.2.4 Effect of moisture content
      4.2.5 Effect of temperature
      4.2.6 Purity of electrolytic chemicals
      4.2.7 Impurities in complementary gas
  4.3 Uncertainty of volume fraction
5 Electrochemical cell design
Annex A (informative) Example of a commercial electrochemical
        cell
Annex B (informative) Schematics of electrolytic cells used
        for gas generation
Annex C (informative) Schematic of electrical supply to gas
        generation cell
Annex D (informative) Decomposition voltages of solutions
        between smooth platinum electrodes
Bibliography

ISO 6145-11:2005 specifies a method for the preparation of calibration gas mixtures by using electrochemical generation of a calibration component and introduction into a complementary gas flow. By alteration of the gas flow or the charge passed through the cell electrolyte, it is possible to change the composition of the gas mixture. The relative expanded uncertainty of the calibration gas content, U, obtained by multiplying the relative combined standard uncertainties by a coverage factor, k = 2, is not greater than 5 %.The method described in ISO 6145-11:2005 is intended to be applied to the preparation of calibration gas mixtures in the volume fraction ranges (0,1 to 250) x 10-6.

Committee
CEN/TC 238
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Current

VDI 2100 Blatt 3:2011-10 Determination of gaseous compounds in ambient air - Determination of indoor air pollutants - Gas chromatographic determination of organic compounds - Active sampling by accumulation on adsorbents - Thermal desorption

ISO/IEC Guide 98:1993 Guide to the expression of uncertainty in measurement (GUM)
ISO 6145-7:2009 Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 7: Thermal mass-flow controllers
ISO 6143:2001 Gas analysis — Comparison methods for determining and checking the composition of calibration gas mixtures
ISO 7504:2015 Gas analysis Vocabulary
ISO 6145-1:2003 Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 1: Methods of calibration

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