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ASTM C 25 : 2019

Superseded

Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

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superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Standard Test Methods for Chemical Analysis of Limestone, Quicklime, and Hydrated Lime

Available format(s)

Hardcopy , PDF

Superseded date

04-24-2024

Language(s)

English

Published date

07-26-2019

1.1 These test methods cover the chemical analysis of high-calcium and dolomitic limestone, quicklime, and hydrated lime.

1.1These test methods cover the chemical analysis of high-calcium and dolomitic limestone, quicklime, and hydrated lime. These test methods are classified as either standard (preferred) or alternative (optional).

1.2The standard test methods are those that employ classical gravimetric or volumetric analytical procedures and are typically those required for referee analyses where chemical specification requirements are an essential part of contractual agreement between buyer and seller.

1.3Alternative or optional test methods are provided for those who wish to use procedures shorter or more convenient than the standard methods for the routine determinations of certain constituents. Optional test methods may sometimes be preferred to the standard test methods, but frequently the use of modern and expensive instrumentation is indicated which may not be accessible to everyone. Therefore, the use of these test methods must be left to the discretion of each laboratory.

1.4The analytical procedures appear in the following order:

Section

     Aluminum Oxide 

15

     Available Lime Index 

28

     Calcium and Magnesium Oxide:

      Alternative EDTA Titration Method 

31

     Calcium Carbonate Equivalent 

33

     Calcium Oxide:

      Gravimetric Method 

16

      Volumetric Method 

17

     Carbon Dioxide by Standard Method 

22

     Combined Oxides of Iron and Aluminum 

12

     Ferrous Iron 

Appendix X5

     Free Calcium Oxide 

Appendix X6

     Free Moisture in Hydrated Lime 

21

     Free Moisture in Limestone 

20

     Free Silica 

29

     Insoluble Matter Including Silicon Dioxide:

      Standard Method 

8

      Optional Perchloric Acid Method 

9

     Insoluble Matter Other Than Silicon Dioxide 

11

     Loss on Ignition 

19

     Magnesium Oxide 

18

     Manganese:

      Bismuthate Method 

Appendix X4

      Periodate (Photometric) Method 

27

     pH Determination of Alkaline Earth Solutions 

34

     Phosphorus:

      Titrimetric Method 

Appendix X3

      Molybdovanadate Method 

26

     Silicon Dioxide 

10

     Strontium Oxide 

Appendix X2

     Sulfur Trioxide 

23

     Total Carbon:

      Direct Combustion-Thermal Conductivity Cell
      Method

32

     Total Carbon and Sulfur:

      Combustion/Infrared Detection Method 

35

     Total Iron:

      Standard Method, Potassium Dichromate
      Titration 

13

      Potassium Permanganate Titration Method 

Appendix X1

      Ortho-Phenanthroline, Photometric Method 

14

     Total Sulfur:

      Sodium Carbonate Fusion 

24

      Combustion-Iodate Titration Method 

25

      Unhydrated Oxides 

30

1.5This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see 9.3, 10.2.1, 18.4.3, 31.6.4.2, X2.3.1, and X5.4.1.1.

1.6This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Committee
C 07
DocumentType
Test Method
Pages
40
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy
Supersedes

ASTM C 1875 : 2018 Standard Practice for Determination of Major and Minor Elements in Aqueous Pore Solutions of Cementitious Pastes by Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES)
ASTM C 737 : 2022 Standard Specification for Limestone for Dusting of Coal Mines
ASTM E 1266 : 2020 Standard Practice for Processing Mixtures of Lime, Fly Ash, and Heavy Metal Wastes in Structural Fills and Other Construction Applications
ASTM D 6249 : 2019 Standard Guide for Alkaline Stabilization of Wastewater Treatment Plant Residuals
ASTM C 141/C141M : 2014 : R2022 Standard Specification for Hydrated Hydraulic Lime for Structural Purposes
ASTM C 602 : 2020 Standard Specification for Agricultural Liming Materials
ASTM D 4373 : 2021 Standard Test Method for Rapid Determination of Carbonate Content of Soils
ASTM C 206 : 2014 : R2022 Standard Specification for Finishing Hydrated Lime
ASTM C 1164 : 2022 Standard Practice for Evaluation of Limestone or Lime Uniformity From a Single Source
ASTM C 911 : 2019 Standard Specification for Quicklime, Hydrated Lime, and Limestone for Selected Chemical and Industrial Uses
ASTM C 207 : 2018 Standard Specification for Hydrated Lime for Masonry Purposes
ASTM D 5050 : 2008 : R2023 Standard Guide for Commercial Use of Lime Kiln Dusts and Portland Cement Kiln Dusts
ASTM C 926 : 2023 Standard Specification for Application of Portland Cement-Based Plaster
ASTM C 1318 : 2015 : REV A : R2020 Standard Test Method for Determination of Total Neutralizing Capability and Dissolved Calcium and Magnesium Oxide in Lime for Flue Gas Desulfurization (FGD)
ASTM C 5 : 2018 Standard Specification for Quicklime for Structural Purposes
ASTM C 1707 : 2018 Standard Specification for Pozzolanic Hydraulic Lime for Structural Purposes
ASTM D 1199 : 1986 : R2020 Standard Specification for Calcium Carbonate Pigments
ASTM C 50/C50M : 2013 : R2019 Standard Practice for Sampling, Sample Preparation, Packaging, and Marking of Lime and Limestone Products
ASTM C 977 : 2018 Standard Specification for Quicklime and Hydrated Lime for Soil Stabilization
ASTM C 821 : 2022 Standard Specification for Lime for Use with Pozzolans
ASTM D 50 : 1990 : R2023 Standard Test Methods for Chemical Analysis of Yellow, Orange, Red, and Brown Pigments Containing Iron and Manganese
ASTM D 1301 : 1991 : R2020 Standard Test Methods for Chemical Analysis of White Lead Pigments
ASTM C 114 : 2022 Standard Test Methods for Chemical Analysis of Hydraulic Cement
ASTM C 1271 : 1999 : R2020 Standard Test Method for X-ray Spectrometric Analysis of Lime and Limestone
ASTM C 1489 : 2015 : R2022 Standard Specification for Lime Putty for Structural Purposes
ASTM D 5759 : 2012 : R2020 Standard Guide for Characterization of Coal Fly Ash and Clean Coal Combustion Fly Ash for Potential Uses
ASTM C 602 : 2023 Standard Specification for Agricultural Liming Materials
ASTM F 3339 : 2020 Standard Guide for Construction or Renovation of Native-soil Athletic Fields
ASTM C 926 : 2023 : REV A Standard Specification for Application of Portland Cement-Based Plaster
ASTM C 1875 : 2018 : R2024 Standard Practice for Determination of Major and Minor Elements in Aqueous Pore Solutions of Cementitious Pastes by Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES)
ASTM C 114 : 2023 Standard Test Methods for Chemical Analysis of Hydraulic Cement
ASTM C 1797 : 2023 : REV A Standard Specification for Ground Calcium Carbonate and Aggregate Mineral Fillers for use in Hydraulic Cement Concrete

ASTM E 177 : 1990 : REV A : R1996 Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods
ASTM E 29 : 2013 : R2019 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
ASTM E 29 : 2002 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
ASTM D 1193 : 1977 : R1983 : EDT 1 Standard Specification for Reagent Water
ASTM C 51 : 2023 Standard Terminology Relating to Lime and Limestone (as Used by the Industry)
ASTM E 691 : 2020 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
ASTM E 70 : 2019 Standard Test Method for pH of Aqueous Solutions With the Glass Electrode
ASTM E 691 : 2019 : EDT 1 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
ASTM E 691 : 2023 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
ASTM D 1193 : 2006 : R2011 Standard Specification for Reagent Water
ASTM E 200 : 2016 Standard Practice for Preparation, Standardization, and Storage of Standard and Reagent Solutions for Chemical Analysis
ASTM E 691 : 2022 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
ASTM E 691 : 2009 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
ASTM D 1193 : 1991 Standard Specification for Reagent Water
ASTM E 200 : 2023 Standard Practice for Preparation, Standardization, and Storage of Standard and Reagent Solutions for Chemical Analysis
ASTM E 691 : 2021 Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
ASTM C 51 : 2001 Standard Terminology Relating to Lime and Limestone (as used by the Industry)
ASTM C 51 : 2021 Standard Terminology Relating to Lime and Limestone (as Used by the Industry)
ASTM D 1193 : 1970 Standard Specification For Reagent Water
ASTM E 173 : 1993 Practice for Conducting Interlaboratory Studies of Methods for Chemical Analysis of Metals (Withdrawn 1997)
ASTM D 1193 : 2006 Standard Specification for Reagent Water
ASTM E 50 : 1982 : R1986 Standard Practices for Apparatus, Reagents, and Safety Precautions for Chemical Analysis of Metals
ASTM D 1193 : 1999 Standard Specification for Reagent Water
ASTM C 51 : 2020 Standard Terminology Relating to Lime and Limestone (as Used by the Industry)
ASTM D 1193 : 2006 : R2018 Standard Specification for Reagent Water
ASTM E 70 : 2024 Standard Test Method for pH of Aqueous Solutions With the Glass Electrode
ASTM C 911 : 2019 Standard Specification for Quicklime, Hydrated Lime, and Limestone for Selected Chemical and Industrial Uses
ASTM E 29 : 2022 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications

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