CEN/TS 16182:2012
Current
The latest, up-to-date edition.
Sludge treated biowaste and soil - Determination of nonylphenols (NP) and nonylphenol-mono- and diethoxylates using gas chromatography with mass selective detection (GC-MS)
22-02-2012
Foreword
Introduction
1 Scope
2 Normative references
3 Principle
4 Interferences
5 Reagents
6 Apparatus
7 Sample storage and sample pretreatment
8 Procedure
9 Calculation and expression of results
10 Precision
11 Test report
Annex A (informative) - Repeatability and reproducibility
data
Annex B (informative) - Example of chromatographic
conditions and example of a chromatogram
Bibliography
This Technical Specification specifies a method for the determination of nonylphenols (NP), nonylphenol-monoethoxylates (NP1EO) and nonylphenol-diethoxylates (NP2EO) in sludge using GC-MS. For sludge a limit of detection of 0,1 mg/kg and for soil and treated bio-waste 0,02 mg/kg (expressed as dry matter) may be achieved.Lower limits of detection may be achieved by concentrating the extract by solvent evaporation.NOTE4-tert-octylphenol can also be analysed with this method.
| Committee |
CEN/TC 444
|
| DocumentType |
Technical Specification
|
| PublisherName |
Comite Europeen de Normalisation
|
| Status |
Current
|
| Standards | Relationship |
| XP CEN/TS 16182 : 2012 XP | Identical |
| S.R. CEN/TS 16182:2012 | Identical |
| DIN CEN/TS 16182;DIN SPEC 91262:2012-05 | Identical |
| ISO 18857-1:2005 | Water quality — Determination of selected alkylphenols — Part 1: Method for non-filtered samples using liquid-liquid extraction and gas chromatography with mass selective detection |
| PREN 15934 : DRAFT 2009 | SOIL, SLUDGE, WASTE, AND TREATED BIOWASTE - DETERMINATION OF DRY MATTER - GRAVIMETRIC METHOD |
| EN ISO 18857-1:2006 | Water quality - Determination of selected alkylphenols - Part 1: Method for non-filtered samples using liquid-liquid extraction and gas chromatography with mass selective detection (ISO 18857-1:2005) |
| ISO 22892:2006 | Soil quality — Guidelines for the identification of target compounds by gas chromatography and mass spectrometry |
| PREN 16179 : DRAFT 2010 | SLUDGE, TREATED BIOWASTE AND SOIL - GUIDANCE FOR SAMPLE PRETREATMENT |
| ISO 18857-2:2009 | Water quality — Determination of selected alkylphenols — Part 2: Gas chromatographic-mass spectrometric determination of alkylphenols, their ethoxylates and bisphenol A in non-filtered samples following solid-phase extraction and derivatisation |
| ISO 16720:2005 | Soil quality — Pretreatment of samples by freeze-drying for subsequent analysis |
| EN ISO 18857-2:2011 | Water quality - Determination of selected alkylphenols - Part 2: Gas chromatographic-mass spectrometric determination of alkylphenols, their ethoxylates and bisphenol A in non-filtered samples following solid-phase extraction and derivatisation (ISO 18857-2:2009) |
| EN ISO 16720:2007 | Soil quality - Pretreatment of samples by freeze-drying for subsequent analysis (ISO 16720:2005) |
| ISO 5725-2:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method |
| ISO 8466-1:1990 | Water quality — Calibration and evaluation of analytical methods and estimation of performance characteristics — Part 1: Statistical evaluation of the linear calibration function |
| EN ISO 22892:2011 | Soil quality - Guidelines for the identification of target compounds by gas chromatography and mass spectrometry (ISO 22892:2006) |