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ASTM D 7423 : 2017

Superseded
Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by
superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Standard Test Method for Determination of Oxygenates in C2, C3, C4, and C5 Hydrocarbon Matrices by Gas Chromatography and Flame Ionization Detection
Available format(s)

Hardcopy , PDF

Superseded date

20-03-2023

Language(s)

English

Published date

10-07-2017

This test method covers the gas chromatographic procedure for the quantitative determination of organic oxygenates in C2, C3, C4, and C5 matrices by multidimensional gas chromatography and flame ionization detection.

1.1This test method covers the gas chromatographic procedure for the quantitative determination of organic oxygenates in C2, C3, C4, and C5 matrices by multidimensional gas chromatography and flame ionization detection. This test method is applicable when the hydrocarbon matrices have a final boiling point not greater than 200 °C. Oxygenate compounds include, but are not limited to, those listed in Table 1. The linear working range for oxygenates is 0.50 mg/kg to 100 mg/kg.

TABLE 1 Oxygenates and Typical Retention Times

Components

Retention Time (min)

Dimethyl ether

6.18

Diethyl ether

8.44

Acetaldehyde

8.89

Ethyl tert-butyl ether

10.66

Methyl tert-butyl ether (MTBE)

10.92

Diisopropyl ether

11.22

Propionaldehyde (Propanal)

12.00

Tertiary amyl methyl ether (TAME)

13.19

Propyl ether

14.00

Isobutylaldehyde

14.10

Butylaldehyde

14.50

Methanol

14.91

Acetone

15.39

Isovaleraldehyde

16.00

Valeraldehyde

16.10

2-Butanone (MEK)

17.14

Ethanol

17.51

N-propyl alcohol and isopropanol

19.20 (co-elution)

Allyl Alcohol

20.00

Isobutanol, Tert-butyl alcohol, Sec-Butanol

20.24 (co-elution)

N-butanol

20.84

1.2This test method is intended to determine the mass concentration of each oxygenate in the hydrocarbon matrix. Oxygenate compound identification is determined by reference standards and column elution retention order.

1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Committee
D 02
DocumentType
Test Method
Pages
9
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy
Supersedes

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ASTM D 6300 : 2002 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 4175 : 2009 : REV A : EDT 2 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
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ASTM D 4175 : 2015 : REV B : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
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