BS EN 16694:2015
Current
The latest, up-to-date edition.
Water quality. Determination of selected polybrominated diphenly ether (PBDE) in whole water samples. Method using solid phase extraction (SPE) with SPE-disks combined with gas chromatography-mass spectrometry (GC-MS)
Hardcopy , PDF
English
30-09-2015
| Committee |
EH/3/2
|
| DevelopmentNote |
Supersedes 13/30291096 DC. (10/2015)
|
| DocumentType |
Standard
|
| Pages |
36
|
| PublisherName |
British Standards Institution
|
| Status |
Current
|
| Supersedes |
This European Standard specifies a method for the determination of six selected polybrominated diphenyl ethers (PBDE) listed in Table 1, representative for technical brominated diphenyl ethers (BDE) in water samples in mass concentrations ≥ 0,025 ng/l for each individual congener. The method uses solid-phase extraction with SPE-disks in combination with gas chromatography-mass spectrometry (GC-MS). It is applicable to the analysis of PBDE in surface water containing suspended particulate matter (SPM) up to 500 mg/l (whole water samples), drinking water and groundwater. The limit of quantification (LOQ) was determined according to ISO/TS 13530, on the basis of replicate determinations of the procedural blank, carried out under reproducibility conditions. This method may be used for the analysis of other BDE congeners not listed in Table 1 or other types of water. However, it is important to verify its applicability before use. Table 1 — Polybrominated diphenyl ethers (PBDE) determined by this method Congener Abbreviationa Formula Molar mass g/mol CAS RNb 2,4,4’-Tribromodiphenyl ether BDE-28 C12H7Br3O 406,8954 41318–75–6 2,2’,4,4’-Tetrabromodiphenyl ether BDE-47 C12H6Br4O 485,7950 5436–43–1 2,2’,4,4’,5-Pentabromodiphenyl ether BDE-99 C12H5Br5O 564,6911 60348–60–9 2,2’,4,4’,6-Pentabromodiphenyl ether BDE-100 C12H5Br5O 564,6911 189084–64–8 2,2’,4,4’,5,6’-Hexabromodiphenyl ether BDE-154 C12H4Br6O 643,5872 68631–49–2 2,2’,4,4’,5,5’-Hexabromodiphenyl ether BDE-153 C12H4Br6O 643,5872 207122–15–4 NOTE EC numbers are not applicable for PBDE congeners. a Numbering analog to IUPAC nomenclature for PCB b CAS RN: Chemical Abstracts Service Registry Number
| Standards | Relationship |
| EN 16694:2015 | Identical |
| DIN EN 16694:2015-12 | Equivalent |
| I.S. EN 16694:2015 | Equivalent |
| EN 16377:2013 | Characterization of waste - Determination of brominated flame retardants (BFR) in solid waste |
| ISO/TS 13530:2009 | Water quality — Guidance on analytical quality control for chemical and physicochemical water analysis |
| ISO 22892:2006 | Soil quality — Guidelines for the identification of target compounds by gas chromatography and mass spectrometry |
| ISO 5667-3:2012 | Water quality — Sampling — Part 3: Preservation and handling of water samples |
| ISO 5667-1:2006 | Water quality — Sampling — Part 1: Guidance on the design of sampling programmes and sampling techniques |
| EN ISO 22032:2009 | Water quality - Determination of selected polybrominated diphenyl ethers in sediment and sewage sludge - Method using extraction and gas chromatography/mass spectrometry (ISO 22032:2006) |
| ISO 5725-2:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method |
| ISO 22032:2006 | Water quality — Determination of selected polybrominated diphenyl ethers in sediment and sewage sludge — Method using extraction and gas chromatography/mass spectrometry |
| EN ISO 5667-3:2012 | Water quality - Sampling - Part 3: Preservation and handling of water samples (ISO 5667-3:2012) |
| ISO 3696:1987 | Water for analytical laboratory use — Specification and test methods |
| ISO 8466-1:1990 | Water quality — Calibration and evaluation of analytical methods and estimation of performance characteristics — Part 1: Statistical evaluation of the linear calibration function |
| EN ISO 3696:1995 | Water for analytical laboratory use - Specification and test methods (ISO 3696:1987) |
| EN ISO 22892:2011 | Soil quality - Guidelines for the identification of target compounds by gas chromatography and mass spectrometry (ISO 22892:2006) |
| EN ISO 5667-1 : 2006 COR 2007 | WATER QUALITY - SAMPLING - PART 1: GUIDANCE ON THE DESIGN OF SAMPLING PROGRAMMES AND SAMPLING TECHNIQUES |
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