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EN 12506:2003

Superseded
Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Characterization of waste - Analysis of eluates - Determination of pH, As, Ba, Cd, Cl-, Co, Cr, Cr Vl, Cu, Mo, Ni, NO2-, Pb, total S, SO42-, V and Zn
Superseded date

01-11-2011

Published date

04-06-2003

Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Sample pre-treatment
5 Blank determination
6 Interference
7 Selection of the suitable test method
8 Expression of results
9 Test report
Annex A (informative) - Validation of EN 12506
      A.1 - General
      A.2 - Interlaboratory study
      A.3 - Selection of laboratories
      A.4 - Selection of samples
      A.5 - Validation scope
      A.6 - Results and statistics
      A.7 - Conclusion
Bibliography

This European Standard specifies methods for the determination of the parameters pH, As, Ba, Cd, Cl-, Co, Cr, Cr VI, Cu, Mo, Ni, NO2-, Pb, total S, SO42-, V and Zn in aqueous eluates for the characterization of waste.

Committee
CEN/TC 292
DevelopmentNote
Supersedes ENV 12506. (06/2003)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Superseded

Standards Relationship
NF EN 12506 : 2004 Identical
BS EN 12506:2003 Identical
NS EN 12506 : 1ED 2003 Identical
SN EN 12506 : 2003 Identical
NBN EN 12506 : 2003 Identical
PN EN 12506 : 2007 Identical
DIN EN 12506:2003-09 Identical
UNE-EN 12506:2004 Identical
UNI EN 12506 : 2004 Identical
NEN EN 12506 : 2003 Identical
I.S. EN 12506:2003 Identical

I.S. EN 62561-7:2012 LIGHTNING PROTECTION SYSTEM COMPONENTS (LPSC) - PART 7: REQUIREMENTS FOR EARTHING ENHANCING COMPOUNDS (IEC 62561-7:2011 (MOD))
PD CEN/TR 16376:2012 Characterization of waste. Overall guidance document for characterization of waste from the extractive industries
08/30185788 DC : DRAFT OCT 2008 BS EN 15864 - CHARACTERISATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERIZATION - DYNAMIC MONOLITHIC LEACHING TEST WITH CONTINUOUS LEACHANT RENEWAL UNDER CONDITIONS RELEVANT FOR SPECIFIED SCENARIO(S)
DD CEN/TS 14997:2006 Characterization of waste. Leaching behaviour tests. Influence of pH on leaching with continuous pH-control
EN 15192:2006 Characterisation of waste and soil - Determination of Chromium(VI) in solid material by alkaline digestion and ion chromatography with spectrophotometric detection
UNE-EN 62561-7:2012 Lightning Protection System Components (LPSC) - Part 7: Requirements for earthing enhancing compounds
DIN EN 15192:2007-02 Characterisation of waste and soil - Determination of Chromium(VI) in solid material by alkaline digestion and ion chromatography with spectrophotometric detection
CEN/TR 16376:2012 Characterization of waste - Overall guidance document for characterization of waste from the extractive industries
CEN/TS 16384:2012 Synthetic sport systems - Leaching test
CEN/TR 16184:2011 Characterization of Waste - State-of-the-art document - Analysis of eluates
CEN/TS 14405 : 2004 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TESTS - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS)
BS EN 50164-7:2008 Lightning protection components (LPC) Requirements for earthing enhancing compounds
04/30114861 DC : 0 BS ISO 21268-2 - SOIL QUALITY - LEACHING - PART 2: BATCH TEST USING A LIQUID TO SOLID RATIO OF 10 L/KG DRY MATTER
10/30233988 DC : 0 BS EN 16192 - CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES
04/30114859 DC : 0 BS ISO 21268-1 - SOIL QUALITY - LEACHING - PART 1: BATCH TEST USING A LIQUID TO SOLID RATIO OF 2 L/KG DRY MATTER
BS EN 62561-7:2012 Lightning Protection System Components (LPSC) Requirements for earthing enhancing compounds
DD CEN/TS 14429:2005 Characterization of waste. Leaching behaviour tests. Influence of pH on leaching with initial acid/base addition
I.S. CEN TS 14429:2005 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TESTS - INFLUENCE OF PH ON LEACHING WITH INITIAL ACID/BASE ADDITION
ISO 15192:2010 Soil quality Determination of chromium(VI) in solid material by alkaline digestion and ion chromatography with spectrophotometric detection
S.R. CEN/TR 16376:2012 CHARACTERIZATION OF WASTE - OVERALL GUIDANCE DOCUMENT FOR CHARACTERIZATION OF WASTE FROM THE EXTRACTIVE INDUSTRIES
DIN EN 13370:2003-09 CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES - DETERMINATION OF AMMONIUM, AOX, CONDUCTIVITY, HG, PHENOL INDEX, TOC, CN[-] EASILY LIBERATABLE, F[-]
BS EN 16192:2011 Characterization of waste. Analysis of eluates
I.S. CEN TS 14405:2004 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TESTS - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS)
09/30179897 DC : 0 BS ISO 15192 - SOIL QUALITY - DETERMINATION OF CHROMIUM(6) IN SOLID MATERIAL BY ALKALINE DIGESTION AND ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION
15/30326969 DC : 0 BS EN 62561-7 ED. 2 - LIGHTNING PROTECTION SYSTEM COMPONENTS (LPSC) - PART 7: REQUIREMENTS FOR EARTHING ENHANCING COMPOUNDS
I.S. EN 15192:2006 CHARACTERISATION OF WASTE AND SOIL - DETERMINATION OF CHROMIUM(6) IN SOLID MATERIAL BY ALKALINE DIGESTION AND ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION
I.S. EN 16192:2011 CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES
UNE-CEN/TR 16184:2011 IN Characterization of Waste - State-of-the-art document - Analysis of eluates
DIN EN 15192 E : 2007 CHARACTERISATION OF WASTE AND SOIL - DETERMINATION OF CHROMIUM(6) IN SOLID MATERIAL BY ALKALINE DIGESTION AND ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION
99/109764 DC : DRAFT DEC 1999 BS EN 12457-1 - CHARACTERIZATION OF WASTE - COMPLIANCE TEST FOR LEACHING OF GRANULAR WASTE MATERIAL AND SLUDGES - PART 1: ONE STAGE BATCH TEST AT A LIQUID TO SOLID RATIO OF 2 L/KG WITH PARTICLE SIZE BELOW 4 MM (WITH OR WITHOUT SIZE REDUCTION)
I.S. EN 13370:2003 CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES - DETERMINATION OF AMMONIUM, AOX, CONDUCTIVITY, HG, PHENOL INDEX, TOC, EASILY LIBERATABLE CN[-], F[-]
PD CEN/TS 16384:2012 Synthetic sport systems. Leaching test
DIN EN 16192:2012-02 Characterization of waste - Analysis of eluates
08/30185785 DC : DRAFT OCT 2008 BS EN 15863 - CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERIZATION - DYNAMIC MONOLITHIC LEACHING TEST WITH PERIODIC LEACHANT RENEWAL, UNDER FIXED TEST CONDITIONS
UNI CEN/TS 16384 : 2012 SYNTHETIC SPORT SYSTEMS - LEACHING TEST
DD CEN/TS 14405:2004 Characterization of waste. Leaching behaviour tests. Up-flow percolation test (under specified conditions)
I.S. EN 50164-7:2008 LIGHTNING PROTECTION COMPONENTS (LPC) - PART 7: REQUIREMENTS FOR EARTHING ENHANCING COMPOUNDS
S.R. CEN/TR 16184:2011 CHARACTERIZATION OF WASTE - STATE-OF-THE-ART DOCUMENT - ANALYSIS OF ELUATES
BS EN 15192:2006 Characterisation of waste and soil. Determination of chromium (VI) in solid material by alkaline digestion and ion chromatography with spectrophotometric detection
BS EN 13370:2003 Characterization of waste. Analysis of eluates. Determination of Ammonium, AOX, conductivity, Hg, phenol index, TOC, easily liberatable CN$u-, F$u-
I.S. CEN TS 14997:2006 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TESTS - INFLUENCE OF PH ON LEACHING WITH CONTINUOUS PH-CONTROL
S.R. CEN/TS 16384:2012 SYNTHETIC SPORT SYSTEMS - LEACHING TEST
04/30116791 DC : DRAFT JUL 2004 BS EN 15002 - CHARACTERISATION OF WASTE - PREPARATION OF TEST PORTIONS FROM LABORATORY SAMPLE
CEI EN 62561-7 : 2012 LIGHTNING PROTECTION SYSTEM COMPONENTS (LPSC) - PART 7: REQUIREMENTS FOR EARTHING ENHANCING COMPOUNDS
05/30133266 DC : DRAFT MAY 2005 BS EN 15192 - CHARACTERISATION OF WASTE AND SOIL - DETERMINATION OF HEXAVALENT CHROMIUM IN SOLID MATERIAL BY ALKALINE DIGESTION AND ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION - COMPLEMENTARY ELEMENT
UNE-EN 16192:2012 Characterization of waste - Analysis of eluates
UNI EN 16192 : 2012 CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES
CEN/TS 14429:2005 Characterization of waste - Leaching behaviour tests - Influence of pH on leaching with initial acid/base addition
CEN/TS 14997 : 2006 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TESTS - INFLUENCE OF PH ON LEACHING WITH CONTINUOUS PH-CONTROL
EN 13370:2003 Characterization of waste - Analysis of eluates - Determination of Ammonium, AOX, conductivity, Hg, phenol index, TOC, easily liberatable CN-, F-
EN 62561-7:2012 Lightning Protection System Components (LPSC) - Part 7: Requirements for earthing enhancing compounds
EN 16192:2011 Characterization of waste - Analysis of eluates
EN 50164-7:2008 Lightning Protection Components (LPC) - Part 7: Requirements for earthing enhancing compounds

ISO/IEC 17025:2005 General requirements for the competence of testing and calibration laboratories
ISO 5725-1:1994 Accuracy (trueness and precision) of measurement methods and results — Part 1: General principles and definitions
EN 12457-2:2002 Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 2: One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 4 mm (without or with size reduction)
EN ISO 11885:2009 Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 11885:2007)
ISO 11083:1994 Water quality — Determination of chromium(VI) — Spectrometric method using 1,5-diphenylcarbazide
ISO/TR 13530:1997 Water quality Guide to analytical quality control for water analysis
EN 26777 : 1993 WATER QUALITY - DETERMINATION OF NITRITE - MOLECULAR ABSORPTION SPECTROMETRIC METHOD
ISO 5725-3:1994 Accuracy (trueness and precision) of measurement methods and results — Part 3: Intermediate measures of the precision of a standard measurement method
ISO 5725-6:1994 Accuracy (trueness and precision) of measurement methods and results — Part 6: Use in practice of accuracy values
EN 12457-4:2002 Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 4: One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 10 mm (without or with size reduction)
ISO 8288:1986 Water quality — Determination of cobalt, nickel, copper, zinc, cadmium and lead — Flame atomic absorption spectrometric methods
ISO 5725-4:1994 Accuracy (trueness and precision) of measurement methods and results Part 4: Basic methods for the determination of the trueness of a standard measurement method
ISO 9297:1989 Water quality Determination of chloride Silver nitrate titration with chromate indicator (Mohr's method)
EN ISO 10304-2 : 1996 WATER QUALITY - DETERMINATION OF DISSOLVED ANIONS BY LIQUID CHROMATOGRAPHY OF IONS - DETERMINATION OF BROMIDE, CHLORIDE, NITRATE, NITRITE, ORTHOPHOSPHATE AND SULFATE, IN WASTE WATER
ENV ISO 13530 : DRAFT 1998 WATER QUALITY - GUIDE TO ANALYTICAL QUALITY CONTROL FOR WATER ANALYSIS
EN 13370:2003 Characterization of waste - Analysis of eluates - Determination of Ammonium, AOX, conductivity, Hg, phenol index, TOC, easily liberatable CN-, F-
EN 12457-1:2002 Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 1: One stage batch test at a liquid to solid ratio of 2 l/kg for materials with high solid content and with particle size below 4 mm (without or with size reduction)
ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
EN ISO 5667-3:2012 Water quality - Sampling - Part 3: Preservation and handling of water samples (ISO 5667-3:2012)
EN 12457-3:2002 Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 3: Two stage batch test at a liquid to solid ratio of 2 l/kg and 8 l/kg for materials with high solid content and with particle size below 4 mm (without or with size reduction)
ISO 10523:2008 Water quality — Determination of pH
EN ISO 11969:1996 WATER QUALITY - DETERMINATION OF ARSENIC - ATOMIC ABSORPTION SPECTROMETRIC METHOD (HYDRIDE TECHNIQUE)
ISO 5725-5:1998 Accuracy (trueness and precision) of measurement methods and results — Part 5: Alternative methods for the determination of the precision of a standard measurement method
EN ISO 10304-1:2009 Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate (ISO 10304-1:2007)
EN ISO 13395 : 1996 WATER QUALITY - DETERMINATION OF NITRITE NITROGEN AND NITRATE NITROGEN AND THE SUM OF BOTH BY FLOW ANALYSIS (CFA AND FIA) AND SPECTROMETRIC DETECTION

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